1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product: BAN Phase Separation Reagent
Cat. No: BN 191
Molecular Research Center, Inc.
5645 Montgomery Rd.
Cincinnati, Ohio 45212
USA 1-888-841-0090
Product Name: BAN Phase Separation Reagent
Chemical Formula: BrC6H4OCH3
Molecular Weight: 187.03
Synonyms: 1-Bromo-4-methoxybenzene;
p-Bromoanisole; p-Anisyl bromide.
NFPA RATINGS: (estimated) Health=1 Fire=1 Reactivity=0
HMIS RATINGS: estimated (scale 0-4) Health=1 Fire=1 Reactivity=1 PPE=H
CHEMTREC EMERGENCY NUMBER: Only in the event of an emergency involving
a spill, leak, fire exposure or accident.
USA: 1-800-424-9300; International: 1-703-527-3887
2. COMPOSITION
/ INFORMATION ON INGREDIENTS
Component CAS
No Percent
4-Bromoanisole 104-92-7 >98 %
EINECS
No.
203-252-1
3. HAZARD
IDENTIFICATION
EMERGENCY
OVERVIEW: A clear to
colorless to pale yellow liquid.
Caution! May cause eye, skin or
respiratory tract irritation. May be
harmful if absorbed through skin, if swallowed or inhaled. No information is currently listed regarding
target organs, hazard symbols or risk phrases.
4. FIRST
AID
EYE
CONTACT: Check for and remove any
contact lenses. Flush eyes with water for 15 min., holding eyelids open. Obtain medical attention.
SKIN
CONTACT: Flush skin with soap and water for 15 min. Remove contaminated clothing and thoroughly wash before
reuse.
INHALATION: Remove from exposure to fresh air
immediately. If not breathing, give
artificial respiration. Obtain medical
attention. Treat symptomatically and
supportively.
INGESTION: If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Do
not induce vomiting unless directed so by medical personnel. Obtain medical
attention. Loosen tight clothing such
as a collar, tie belt or waistband.
5. FIRE
FIGHTING MEASURES
EXTINGUISHING
MEDIA: May be combustible at
high temperatures. Extinguishing media
appropriate to surrounding fire conditions.
Small Fire: Use dry chemical powder. Large Fire: Use water spray, fog or
foam. Do not use water jet. May emit
toxic fumes under fire conditions (bromide).
Vapors may be heavier than air and they can spread along the floor and
collect in low or confined areas.
SPECIAL
FIRE FIGHTING PROCEDURES: Wear
self-contained breathing apparatus and protective clothing to prevent contact
with skin and eyes. In a fire,
protective gear and a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent) is recommended.
6. ACCIDENTAL
RELEASE MEASURES
PERSONAL
PROTECTIVE EQUIPMENT FOR SPILL CONDITIONS: Note that accidental releases may be subject to special state or local
reporting requirements and other regulatory mandates. Check and comply with local laws and regulations. Use gloves and other appropriate protective
covering to avoid skin contact. Ensure adequate ventilation. Use goggles, face shield or other eye
protection. Contain spill with an inert
adsorbent such as vermiculite, sand or earth.
Place spill material in a suitable container and hold for disposal. Avoid breathing vapor, mist or gas.
7. HANDLING
AND STORAGE
Store in a cool, dry place in sealed
containers. Ensure good ventilation at
the workplace. Practice good laboratory techniques when handling this
substance. After using the chemical,
wash hands thoroughly. Use adequate
ventilation and avoid breathing vapor, mist or gas. Empty containers pose a fire risk and any residue should be
evaporated under a fume hood. Keep away
from incompatibles such as oxidizing agents, metals and alkali.
8. EXPOSURE
CONTROLS / PERSONAL PROTECTION
For routine operations wear safety glasses,
latex gloves and a chemical apron to avoid contact with eyes, skin and
clothing. Facilities utilizing this
chemical should be equipped with an eyewash station and safety shower. Use adequate ventilation to keep airborne
concentrations below the permissible exposure limits. (No PELS are listed for this chemical). Personal Protective Equipment: Chemical splash goggles,
protective gloves and clothing to prevent eye and skin exposure.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear,
colorless to pale yellow liquid
Odor: pungent
Vapor Pressure: not reported
Density: 1.4940
g/cm3
Boiling point: 223 C @760 mm Hg (433.4 F)
Melting point: 9-10 C (50 F)
Flash point: 94
C (201.20 F)
Solubility in water: Immiscible
10.
STABILITY AND REACTIVITY
Stable under normal temperatures and
pressures.
INCOMPATIBILITIES: Heat, ignition sources, strong acids, strong
oxidizing agents.
DECOMBUSTION
PRODUCTS: Carbon monoxide, carbon
dioxide, and hydrogen bromide gas.
Hazardous polymerization reactions have not been reported.
11. TOXICOLOGICAL
INFORMATION
RTECS# BZ8501000 CAS# 104-92-7
Rat: Inhalation: oral LD50=3800 mg/kg; LD50
(skin) 3200 mg/kg. Mouse: oral LD50=2200 mg/kg.
Inhalation LC50 20 mg/m3.
CARCINOGENICITY: Not listed by ACGIH, IARC, NTP or CA Prop
65.
To the best of our knowledge the acute and
chronic toxicity of this substance is not fully known.
12.
ECOLOGICAL INFORMATION
ECOTOXICITY: Bacteria: Phytobacterium phosphoreum, EC50
2.25-2.58 mg/L; 5, 15 and 30 minutes.
Microtox test, 15 C. General
Notes: Do not allow product to be released into ground water or sewage system.
13. DISPOSAL
CONSIDERATIONS
Keep in sealed containers until final
disposal. Dispose of in a manner
consistent with federal, state and local regulations. Not listed as banned from
land disposal according to RCRA.
14. TRANSPORT
INFORMATION
Not a hazardous matter for transportation.
Not regulated for
domestic US DOT transport or Canada TDG.
15. REGULATORY
INFORMATION
European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols: Not available
Risk/Safety Phrases: S24/25 Avoid contact with skin and eyes.
WGK (Water Danger/ Protection) CAS #
1104-92-7 Not available.
United Kingdom Occupational Exposure Limits
Canada: CAS# 104-92-7 is listed in Canada’s
DSL List. WHMIS classification D2L..
US Federal:
TSCA: CAS # 104-92-7 is listed on the TSCA
inventory.
Health and Safety Reporting: The chemical is
not on the health & safety reporting list.
Chemical Test Rules: This chemical is not
under a chemical test rule.
Section 12b: This chemical is not listed
under TSCA Section 12b.
TSCA Significant New Use Rule: This chemical
is not listed under SNUR.
CERCLA Hazardous Substances and corresponding
RQ’s: This chemical does not have an RQ
SARA Section 302 Extremely Hazardous
Substances: no listed TPQ.
SARA Codes: CAS# 104-92-7: immediate,
reactive.
Section 313: Not reported under section 313.
Clean Air Act: The chemical is not classified
as a hazardous air pollutant or a Class 1or 2 ozone depletory.
Clean Water Act: This chemical is not listed as a hazardous substance, priority pollutant or a toxic pollutant under the CWA.
State: CAS # 104-92-7 is not listed or
present on CA, PA, MN, MA, FL or NJ state lists.
16. OTHER
INFORMATION
Reviewed
by BW, MJ
Creation
date 11/1/07
Revision date 2/01/09
This information is believed to be accurate
and represents the information currently available to us. However, we make no
warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use.
Users should make their own investigations to determine the suitability of the
information for their particular purposes.
Abbreviations:
N/A Not
Applicable
N.D.A. No data
available
TLV-STEL Threshold
Limit Values (Short-Term Exposure Limit)
TLV-TWA Threshold
Limit Values (Time-Weighted Average)
OSHA PEL-TWA OSHA
Permissible Exposure Level